Here's my advice, take it for what it's worth.
Start with short focal length imaging. This means you are a bit better off staying away from the standard SCT's. It is far easier to acquire good images, center objects on the chip, etc. with a shorter focal length than with a longer focal length.
When starting out in CCD imaging, you need to focus on learning the basics or you will never get anywhere. With a short FL, you can easily master guiding, focusing, etc. and then spend the most time where it is needed--image processing. Learning image processing is one of the most difficult parts of CCD imaging. Plan to spend a lot of time learning good processing technique.
A second major thing to make sure you get right is your mount. A good quality mount, properly rated for your load, is critical. I would stay away from the CI-700 or GP. They are of lower quality, and you will spend a lot of time just trying to make them work well. The Losmandy mounts now have an improved worm, and the quality is much better. If you have the money, spend as much as you can on the mount. The AP600 is a great choice, but if you want to get a mount that can carry heavier loads in the future, try the 900. The Takahashi mounts are excellent, but a bit clunkier to use--no nice keypads, etc--although they do work very well with The Sky. I would recommend an EM-200 or NJP-160.
As for the CCD, the Starlight cameras are OK, but stay away from the single-shot color. The colors are never very good from these cameras; you are far better off with color filters and a monohrome CCD. The HX-916 would fit here. Frankly, I would steer you towards the new SBIG ST-2000XM. The main reason people have bought the Starlight Express cameras in the past was that they were less expensive. The new SBIG ST-2000 uses the same inexpensive Sony CCD as many of the SX cameras, and also has the built-in guider chip. Anyone who does not like this feature has never used it...it is incredible to have a built-in off-axis guiding chip. It is also very easy to use for a beginner and solves a ton of problems caused by off-axis guiding.
The concepts are simple--keep it simple but high quality and the initial learning curve will be smaller and the results more gratifying. You can move up to more difficult types of imaging later--like the long FL hi-res work. Your TV-102 is a great place to start. In fact, my first telescope that I learned to image with was a TV-102 several years ago...
Hope this helps a little,
Jeff Hapeman
Jeff 8O